|
|
3''-phosphoadenylyl-sulfate + trehalose <=> adenosine_3,5''-bisphosphate + 2-O-sulfo-alpha,alpha-trehalose + H+
|
2.8.2.37
trehalose 2-sulfotransferase
2.8.2.8
[heparan sulfate]-glucosamine N-sulfotransferase
|
–
–
|
|
BRENDA:
BR50889
KEGG:
R10971
MetaCyc:
RXN-15426
SABIO-RK:
13124
|
|
|
|
C37-hydroxyphthioceranyl-[(hydroxy)phthioceranate_synthase] + 2''-palmitoyl-2-O-sulfo-alpha,alpha-trehalose <=> SL1278 + a_holo-[(hydroxy)phthioceranic_acid_synthase]
|
2.3.1.283
2'-acyl-2-O-sulfo-trehalose (hydroxy)phthioceranyltransferase
|
–
|
|
MetaCyc:
RXN-17319
|
|
|
|
palmitoyl-[acyl-carrier_protein] + CoA <=> palmitoyl-CoA + [acyl-carrier_protein]
|
2.3.1
2.3.1.85
fatty-acid synthase system
2.3.1.86
fatty-acyl-CoA synthase system
|
–
–
–
|
|
BRENDA:
BS456174
KEGG:
R10700
MetaCyc:
RXN3O-9780
|
|
|
|
a_palmitoyl-[(hydroxy)phthioceranic_acid_synthase] + (S)-methylmalonyl-CoA + NADPH + H+ <=> C37-hydroxyphthioceranyl-[(hydroxy)phthioceranate_synthase] + CoA + CO2 + NADP+ + H2O
|
2.3.1.287
phthioceranic/hydroxyphthioceranic acid synthase
|
–
|
|
MetaCyc:
RXN-17323
|
|
|
|
SL1278 <=> sulfolipid-2 + 2''-palmitoyl-2-O-sulfo-alpha,alpha-trehalose
|
2.3.1.284
3'-(hydroxy)phthioceranyl-2'-palmitoyl(stearoyl)-2-O-sulfo-trehalose (hydroxy)phthioceranyltransferase
|
–
|
|
MetaCyc:
RXN-17317
|
|
|
|
palmitoyl-CoA + 2-O-sulfo-alpha,alpha-trehalose <=> 2''-palmitoyl-2-O-sulfo-alpha,alpha-trehalose + CoA
|
2.3.1.288
2-O-sulfo trehalose long-chain-acyltransferase
|
–
|
|
BRENDA:
BR52828
KEGG:
R12466
MetaCyc:
RXN-17318
|
|
|
|
a_long-chain_acyl-adenylate_ester + a_holo-[(hydroxy)phthioceranic_acid_synthase] <=> a_palmitoyl-[(hydroxy)phthioceranic_acid_synthase] + AMP + H+
|
6.2.1.57
long-chain fatty acid adenylase/transferase FadD23
|
–
|
|
BRENDA:
BR52759
MetaCyc:
RXN-18540
|
|
|
|
palmitate + ATP + H+ <=> a_long-chain_acyl-adenylate_ester + diphosphate
|
6.2.1.49
long-chain fatty acid adenylyltransferase FadD28
6.2.1.57
long-chain fatty acid adenylase/transferase FadD23
|
–
–
|
|
BRENDA:
BR52065
KEGG:
R12396
MetaCyc:
RXN-17320
|
|
|
|
palmitoyl-[acyl-carrier_protein] + H2O <=> fatty_acid + [acyl-carrier_protein] + H+
|
2.3.1.85
fatty-acid synthase system
3.1.2.14
oleoyl-[acyl-carrier-protein] hydrolase
3.1.2.21
dodecanoyl-[acyl-carrier-protein] hydrolase
|
–
–
–
|
|
BRENDA:
BS12701;
BS364432;
BS382837;
BS432386
KEGG:
R01706;
R08163;
R12329
MetaCyc:
RXN-17108;
RXN-7902;
RXN-9548;
RXN-9549
|
|